Key Concepts
Force: Strength or energy as an attribute of physical action or movement.
Work: Activity involving mental or physical effort done to achieve a result.
Power: The ability or capacity to do something or act in a particular way.
Energy: The ability to do work.
Volume:
- Definition: Occupied space by a substance.
- Effect of Temperature: Change in temperature affects the volume of solids and liquids.
Pressure
- Definition: Scientifically, pressure is a force per unit area.
- Types of Pressure:
- Atmospheric Pressure: Pressure exerted by the atmosphere.
- Gauge Pressure: Difference between actual pressure and atmospheric pressure.
- Absolute Pressure: Sum of atmospheric pressure and gauge pressure.
- Vacuum Pressure: Pressure below atmospheric pressure.
Temperature
- Definition: The degree of hotness or coldness of a body.
- Measurement: Measured using a thermometer, which works on the principle of change in volume with temperature.
- Common Thermometers: Mercury and alcohol thermometers.
Temperature Scales:
Heat
- Definition: A form of energy that gives the sensation of warmth or hotness.
- Effects of Heat:
- Increase in temperature.
- Change of state (melting or vaporizing).
Modes of Heat Transfer
- Conduction: Transfer of heat from molecule to molecule.
- Convection: Transfer of heat by upward currents caused by heat.
- Radiation: Transfer of heat by waves.
Sensible and Latent Heat
- Sensible Heat: Causes a change in temperature.For solids, liquids, and vapors.
- Latent Heat: Causes a change of state without a change in temperature.
- Latent Heat of Fusion: Heat needed to change 1 kg of solid to liquid.
- Latent Heat of Vaporization: Heat needed to change 1 kg of liquid to vapor.
- Latent Heat of Sublimation: Heat needed to change 1 kg of solid to gas.
Comparison of Heat and Work
- Heat: Random motion of molecules.
- Work: Ordered motion in one direction.
- Conversion: Work can be converted to heat, but not vice versa (Second Law of Thermodynamics).
Laws of Thermodynamics
Overview
- Thermodynamics deals with the relations between heat, work, and properties of systems.
- It is based on empirical laws formed by experimentation.
The Four Laws of Thermodynamics
- Zeroth Law: If two systems are in thermal equilibrium with a third system, they are in thermal equilibrium with each other.
- First Law: Energy cannot be created or destroyed, only transformed.
4.Third Law: Absolute zero is a state of zero motion and cannot be reached.
Thermodynamic Processes
- Adiabatic: No heat transferred ($Q = 0$).
- Isothermal: Constant temperature.
- Isobaric: Constant pressure.
- Isochoric: Constant volume.
Process Equations
Applications
- Refrigeration and Heat Pumps: Based on the principle of reversed Carnot cycle.
- Heat Transfer: Heat can flow from low to high temperature only with external work supplied.
Carnot Cycle and Thermodynamic Principles
Carnot Cycle
- The Carnot cycle is a theoretical model for heat engines.
- It involves:
- Absorbing heat from a high-temperature reservoir.
- Releasing heat to a low-temperature reservoir.
- Producing work in the process.
Reversed Carnot Cycle.
- In the reversed Carnot cycle:
- Work is supplied to the system.
- Heat is transferred from a low-temperature reservoir to a high-temperature reservoir.
- This process is explained by the second law of thermodynamics.
Applications
Refrigerators:
- Freezers maintain low temperatures by removing heat and releasing it to the atmosphere.
- Requires electricity to run the compressor.
Air Conditioners:
- Cool rooms by removing heat from the indoor air.
Heat Pumps:
- Heat rooms by absorbing heat from the outside atmosphere.
Thermodynamic Cycles
A thermodynamic cycle consists of processes that transfer heat and work, changing pressure and temperature, and returning to the initial state.
Types of Thermodynamic Cycles
Reversible Cycle:
- Processes can be reversed without loss of energy.
- No heat loss due to friction or other factors.
- Initial conditions are restored at the end of the cycle.
Irreversible Cycle:
- Processes cannot be reversed completely.
- Energy loss occurs due to friction, conduction, or radiation.
- Initial conditions are not restored.
Key Concepts
Enthalpy (H)
- A measure of energy in a thermodynamic system.
- Defined as: H = U + PV where U is internal energy, P is pressure, and V is volume.
Entropy (S)
- A measure of disorder in a system.
- Increases with added heat and decreases with heat removal.
- Important for understanding heat transfer in thermodynamics.
Principle of Refrigeration
- Lowers the temperature of a space below the surrounding atmosphere.
- Requires extracting heat to maintain the desired temperature.
Classification of Refrigeration Systems
Direct Expansion (DX) Systems
Centrifugal Chillers
Screw Chillers
Absorption Systems
Heat Pumps
Types of Refrigeration Systems
- Vapor Compression Refrigeration Systems
- Vapor Absorption Refrigeration Systems
- Gas Cycle Refrigeration Systems
- Steam Jet Refrigeration Systems
- Solar Energy-Based Refrigeration Systems
- Thermoelectric Refrigeration Systems
Vapor Compression Refrigeration System
- Also known as mechanical refrigeration.
- Involves a compressor to produce mechanical energy.
- Working of Vapor Compression Refrigeration System
- Refrigerant is stored at high pressure in the receiver.
- High-pressure liquid refrigerant is released to evaporator coils.
- Liquid refrigerant expands and absorbs heat, turning into vapor.
- Vapor enters the compressor, where it is compressed to high pressure and temperature.
- Hot vapor passes to the condenser, where it cools and condenses into liquid.
- Liquid refrigerant returns to the receiver, completing the cycle.
Parts of the Vapor Compression Refrigeration System
Receiver: Storage tank for refrigerant.
Flow Control Devices: Regulate refrigerant flow to the evaporator.
Evaporator: Where refrigerant absorbs heat and changes to vapor.
Suction Line: Connects evaporator to compressor.
Compressor: Pumps refrigerant through the system.
Discharge Line: Connects compressor to condenser.
Condenser: Cools and condenses refrigerant vapor.
Advantages and Disadvantages
Advantages:
- Smaller size for given capacity.
- Lower running costs.
- High coefficient of performance.
Disadvantages:
- High initial cost.
- Leakage prevention is a major concern.
- Vapor Absorption Refrigeration System
- Uses heat energy instead of mechanical energy.
Components:
- Boiler/Generator: Similar to the compressor in vapor compression systems.
- Condenser and Evaporator: Serve the same purpose as in vapor compression systems.
- Absorber: Absorbs low-pressure refrigerant vapor.
Functioning
- Ammonia vapor is absorbed in the absorber by a weak solution.
- The strong solution is heated in the generator to expel ammonia gas.
- The cycle continues as the weak solution is pumped back to the absorber
This summary provides a concise overview of the Carnot cycle, thermodynamic principles, refrigeration systems, and their components.
Refrigeration Systems
Vapor Compression System
Main Components:
- Compressor
- Condenser
- Receiver
- Refrigerant control device
- Evaporator
- The system operates by compressing refrigerant gas, which increases its pressure and temperature.
- Heat is removed from the refrigerant in the condenser, turning it back into a liquid.
- The liquid refrigerant then passes through an expansion valve, reducing its pressure before entering the evaporator
Characteristics:
- Noisy in operation.
- Contains many moving parts, leading to potential wear and tear.
- Requires mechanical energy input, typically from electric motors, diesel, or petrol engines.
- Uses steel or copper tubes for connections.
- More efficient but occupies more space.
- Charging of refrigerant is quite simple.
Vapor Absorption System
Main Components:
- Generator
- Rectifier
- Condenser
- Absorber
- Evaporator
- Heat is added to the generator from a heating source (e.g., gas burner or steam).
- A strong solution is created in the generator and then condensed into a liquid in the condenser.
- The liquid is passed to the receiver and then to the absorber after ammonia is expelled.
Characteristics:
- Quiet in operation.
- No moving parts, minimizing wear and tear or sticking.
- Energy input is mainly heat (from gas, kerosene, or electric heaters).
- Steel tubes are used for connections.
- Pressure is reduced using hydrogen gas.
- The flow of gas depends on gravity and the operation of the generator.
- Charging of refrigerant to the system is difficult.
- Generally less efficient compared to vapor compression systems.
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